Three self-penetrated, interlocked, and polycatenated supramolecular isomers via one-pot synthesis and crystallization |
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| Authors: | Hu Jin-Song Qin Ling Zhang Ming-Dao Yao Xiao-Qiang Li Yi-Zhi Guo Zi-Jian Zheng He-Gen Xue Zi-Ling |
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| Institution: | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P.R. China. |
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| Abstract: | Three supramolecular isomers, {Cd(2)(TPOM)(hfipbb)(2)]·x/y/zsolvent}(n) (1-3), have been synthesized and characterized by one-pot reaction. Even though the compositions of 1-3 are the same, they generate different structures. Reactions over various time periods were found to influence the formation of supramolecular isomers, and there is little influence on this system under other conditions. |
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