New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation |
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| Authors: | Mougel Victor Pécaut Jacques Mazzanti Marinella |
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| Institution: | Laboratoire de Reconnaissance Ionique et Chimie de Coordination, SCIB, UMR-E 3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France. |
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| Abstract: | U(IV) promotes the disproportionation of otherwise stable uranyl(V) Schiff base complexes affording U(IV)-U(V) oxo clusters with new geometries and the first example of a U(IV)···UO(2)(+) cation-cation interaction. |
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