Temperature-directed structural recurrence in low-symmetric Co(II) complexes and nanocrystals |
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| Authors: | Yin Yan-Yan Chen Xiao-Yan Cao Xiao-Chang Shi Wei Cheng Peng |
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| Affiliation: | Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071, China. |
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| Abstract: | Low-symmetric complexes {[Co(μ(2)-L)(H(2)O)(2)]·H(2)O}(n) (1) and {[Co(μ(3)-L)(H(2)O)]·0.5H(2)O}(n) (2) and corresponding nanocrystals were obtained, which exhibit structural recurrence behaviour at various temperatures as well as changes of chiral, nonlinear optical and ferroelectric properties. |
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