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Discotic hexa-peri-hexabenzocoronenes with strong dipole: synthesis, self-assembly and dynamic studies
Authors:Chen Long  Dou Xi  Pisula Wojciech  Yang Xiaoyin  Wu Dongqing  Floudas George  Feng Xinliang  Müllen Klaus
Institution:Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Abstract:Strong dipole moments have been built into two hexa-peri-hexabenzocoronene (HBC) derivatives (1 and 2) originating from the push-pull structure of the molecules with one electron-donating and one electron-withdrawing substituent. The influence of dipole moment on the self-assembly of HBCs in solution and in bulk has been investigated.
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