Enantioselective total synthesis of (+)-scuteflorin A using organocatalytic asymmetric epoxidation |
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| Authors: | Bartlett Christopher J Day David P Chan Yohan Allin Steven M McKenzie Michael J Slawin Alexandra M Z Page Philip C Bulman |
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| Affiliation: | School of Chemistry, University of East Anglia , Norwich Research Park, Norwich, Norfolk NR4 7TJ, UK. |
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| Abstract: | We report the first enantioselective total synthesis of (+)-scuteflorin A in 14% overall yield, employing a chiral iminium salt to effect an organocatalytic asymmetric epoxidation of xanthyletin in >99% ee as the key step. |
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