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Enantiospecific first total synthesis and confirmation of the relative and absolute stereostructure of isocalamusenone
Authors:Adusumilli Srikrishna  Vijendra H Pardeshi  Konda Mahesh
Institution:Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India
Abstract:The enantiospecific total synthesis of two epimers of the sesquiterpene isocalamusenone has been accomplished starting from the readily available monoterpene (R)-limonene, which of the natural product established the stereostructure and the absolute configuration.
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