A formal,stereoselective synthesis of the natural tetrahydropyran derivative ophiocerin D |
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| Authors: | Julián Paños Juan Murga Eva Falomir Miguel Carda J Alberto Marco |
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| Institution: | 1. Depart. de Q. Inorgánica y Orgánica, Univ. Jaume I, 12071 Castellón, Spain;2. Depart. de Q. Orgánica, Univ. de Valencia, 46100 Burjassot, Valencia, Spain |
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| Abstract: | A short, formal stereoselective synthesis of the naturally occurring tetrahydropyran derivative ophiocerin D is reported. The four stereocenters of the molecule were created with the aid of two Sharpless asymmetric dihydroxylations. |
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