An escapade in the world of sulfenate anions: generation,reactivity and applications in domino processes |
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| Authors: | Guillaume Maitro Guillaume Prestat David Madec Giovanni Poli |
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| Institution: | 1. UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, FR2769, Case 183, F-75252, Paris Cedex 05, France;2. Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Paul Sabatier, 118 route de Narbonne, Fr-31062, Toulouse Cedex 9, France |
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| Abstract: | An escapade in the world of sulfenate anions is described and shows that these nucleophiles, despite being described as unstable species, are mild and efficient sulfinylating agents, allowing access to a variety of allyl and aryl sulfoxides under smooth and operationally very simple conditions. Their use in asymmetric catalysis is also possible allowing the preparation of enantio-enriched sulfoxides. Moreover, such anions have been involved in the development of two new pseudo–domino processes. |
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