A common strategy for the synthesis of (+)-gabosine N, (+)-gabosine O,and some carbapyranoses using a Nozaki–Hiyama–Kishi reaction and RCM |
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Authors: | J Prasada Rao B Venkateswara Rao |
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Institution: | Organic III division, Indian Institute of Chemical Technology, Tarnaka, Hyderabad 500 607, India |
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Abstract: | Stereoselective synthesis of carbasugars (+)-gabosine N 1 and (+)-gabosine O 2, carba-α-l-rhamnose 17, and carba-6-deoxy-α-l-talose 18 by using a Nozaki–Hiyama–Kishi (NHK) reaction and ring-closing metathesis. |
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