Development of a palladium catalyzed addition of boronic acids to alkynyl esters: synthesis of trisubstituted olefins as single isomers |
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| Authors: | Alexander Graham Bush |
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| Institution: | Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON, K1N6N5, Canada |
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| Abstract: | Very small phosphine ligands allow access to single isomer trisubstituted olefins from alkynyl esters with complete control of both stereochemistry and regiochemistry. This method provides a convenient synthesis of single isomer trisubstituted olefins without requiring olefin templates. |
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