Preparation and examination of calcium ion-selective electrodes for flow analysis |
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Authors: | Hiroko Wada Tadao Ozawa Genkichi Nakagawa Yasukazu Asano Satoshi Ito |
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Institution: | Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya Japan;Denkikagaku-keiki Co. Ltd., Kichijojikitamachi, Musashinoshi, Tokyo Japan |
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Abstract: | The preparation of calcium ion-selective electrodes based on known alkylphenylphosphate exchangers or on the ETH 1001 ionophore, and their use in a flow-through cell in a flow-injection system for the determination of calcium are described. The response and lifetime of the electrodes and the effects of magnesium and sodium ions on the determination of 10?3?10?5 M calcium are examined in detail. The ionophore electrode is shown to be most satisfactory. |
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