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Cation selectivity of 13-crown-4 and bis(13-crown-4) derivatives
Authors:N.G. Lukyanenko  N.Yu. Nazarova  O.S. Karpinchik  O.T. Melnik
Affiliation:A.V. Bogatsky Physicochemical Institute, Academy of Sciences of the Ukrainian SSR, 270080 Odessa U.S.S.R.
Abstract:The cation selectivity of liquid-membrane electrodes based on 18 derivatives of 13- crown-4 and bis(13-crown-4) is reported. When these compounds are dissolved in 1,2-dichlorobenzene, the electrodes exhibit MgCl+ selectivity which depends on the nature of the bonds connecting the crown ether rings.
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