Influence of a periodic field on the distant electron transfer in biological systems. |
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Authors: | E G Petrov |
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Affiliation: | Bogolyubov Institute for Theoretical Physics, Ukrainian National Academy of Science, Kiev. |
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Abstract: | Generalization of the Marcus transfer rate is derived for the case of a dissipative long-range donor-acceptor electron transfer (ET) mediated by specific bridging electron pathways in biological systems and driven by ac-electric field. High-frequency electric field is shown to block and even to invert the transfer if a specific relation between amplitude and frequency of the ac-field is fulfilled. |
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