Synthesis of electron-poor hexa-peri-hexabenzocoronenes |
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| Authors: | David J Jones Balaji Purushothaman Shaomin Ji Andrew B Holmes Wallace W H Wong |
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| Institution: | Bio21 Institute, School of Chemistry, University of Melbourne, 30 Flemington Road, Parkville, Victoria 3010, Australia. djjones@unimelb.edu.au |
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| Abstract: | The oxidative cyclodehydrogenation of electron-poor arenes was achieved using DDQ-CF(3)SO(3)H resulting in hexa-peri-hexabenzocoronenes with electron withdrawing Br, F and CF(3) groups. This method will lead to their expansion into a new class of electron transport materials. |
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