Selective reduction of 6-substituted 1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes |
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Authors: | I. E. Yakunina A. N. Shchukin M. V. Kopyshev I. V. Shakhkel’dyan A. N. Shumskii A. A. Yakovenko K. A. Lysenko Yu. M. Atroshchenko |
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Affiliation: | 1.Tolstoy Tula State Pedagogical University,Tula,Russia;2.Asineks Ltd.,Moscow,Russia;3.Research Institute of Chemical Diversity,Khimki, Moscow oblast,Russia;4.Nesmeyanov Institute of Organometallic Compounds,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | Reduction of 6-substituted 1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes gives either saturated 1,5-diamino-3-azabicyclo[3.3.1]nonane or unsaturated 1,5-diamino-3-azabicyclo[3.3.1]non-6-enes, depending on the conditions and nature of substituent in the substrate. |
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