Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles |
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| Authors: | Horneff Tony Chuprakov Stepan Chernyak Natalia Gevorgyan Vladimir Fokin Valery V |
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| Affiliation: | Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA. |
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| Abstract: | Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates. |
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