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Self-assembly of a chiral carbonate- and cytidine-containing dodecanuclear copper(II) complex: a multiarm-supplied globular capsule
Authors:Armentano Donatella  Marino Nadia  Mastropietro Teresa F  Martínez-Lillo José  Cano Joan  Julve Miguel  Lloret Francesc  De Munno Giovanni
Institution:Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, 87036 Rende, Cosenza, Italy.
Abstract:A dodecanuclear copper(II) globular-shaped structure has been obtained with the cytidine nucleoside and the templating carbonate anion. It shows receptor properties through anion-cation and multiple anion-pi interactions toward ClO 4 (-) as well as an overall antiferromagnetic coupling.
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