Self-assembly of a chiral carbonate- and cytidine-containing dodecanuclear copper(II) complex: a multiarm-supplied globular capsule |
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Authors: | Armentano Donatella Marino Nadia Mastropietro Teresa F Martínez-Lillo José Cano Joan Julve Miguel Lloret Francesc De Munno Giovanni |
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Institution: | Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, 87036 Rende, Cosenza, Italy. |
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Abstract: | A dodecanuclear copper(II) globular-shaped structure has been obtained with the cytidine nucleoside and the templating carbonate anion. It shows receptor properties through anion-cation and multiple anion-pi interactions toward ClO 4 (-) as well as an overall antiferromagnetic coupling. |
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