Anion-pi-pi interactions in a dinuclear M2L2 metallocycle |
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Authors: | Capó Magdalena Benet-Buchholz Jordi Ballester Pablo |
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Affiliation: | Departament de Química, Universitat de les Illes Balears, 7122 Palma de Mallorca, Spain. magdalena.capo@uib.es |
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Abstract: | The combination of the square-planar cis-protected [Pt(dppp)(O 3SCF 3) 2] (M) with the ditopic N, N'-bis(3,5-dimethyl-4-pyridinyl)-4-ethoxy-2,6-pyridinedicarboxamide ligand (L) leads both in solution and in the solid state to the quantitative self-assembly of a M 2L 2 metallocycle. We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion-pi-pi interactions. |
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