An arene-stabilized cobalt(I) aryl: reactions with CO and NO |
| |
| Authors: | Lei Hao Ellis Bobby D Ni Chengbao Grandjean Fernande Long Gary J Power Philip P |
| |
| Institution: | Department of Chemistry, University of California, Davis, California 95616, USA. |
| |
| Abstract: | The half-sandwich cobalt(I) complex (eta (6)-C 7H 8)CoAr*-3,5- ( i )Pr 2 (Ar*-3,5- ( i )Pr 2 = -C 6H-2,6-(C 6H 2-2,4,6- ( i )Pr 3) 2-3,5- ( i )Pr 2) was synthesized by reduction of 3,5- ( i )Pr 2Ar*Co(mu-Cl)] 2 in toluene. It reacts with CO or NO to afford the unusual complexes 3,5- ( i )Pr 2Ar*C(O)Co(CO)] or 3,5- ( i )Pr 2Ar*N(NO)OCo(NO) 2]. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
