| Research on Crystal Structure of the Complex of 10－Hydroxy－10－（3－indolyl）－9－phenanthrenone with Tetrahydrofuran |
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| 引用本文： | Meng Ji-Ben,Wen Zhong,Wang Yong-Mei,Wang Ru-Ji,Wang Hong-Gen(Department of Chemistry and Central Laboratory,Nankai University,Tianjin,300071). Research on Crystal Structure of the Complex of 10－Hydroxy－10－（3－indolyl）－9－phenanthrenone with Tetrahydrofuran[J]. 结构化学, 1994, 0(2) |
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| 作者姓名： | Meng Ji-Ben Wen Zhong Wang Yong-Mei Wang Ru-Ji Wang Hong-Gen(Department of Chemistry and Central Laboratory Nankai University Tianjin 300071) |
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| 作者单位： | Department of Chemistry and Central Laboratory，Nankai University，Tianjin，300071 |
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| 摘 要： | ＲｅｓｅａｒｃｈｏｎＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆｔｈｅＣｏｍｐｌｅｘｏｆ１０－Ｈｙｄｒｏｘｙ－１０－（３－ｉｎｄｏｌｙｌ）－９－ｐｈｅｎａｎｔｈｒｅｎｏｎｅｗｉｔｈＴｅｔｒａｈｙｄｒｏｆｕｒａｎＭｅｎｇＪｉ－Ｂｅｎ；ＷｅｎＺｈｏｎｇ；Ｗａｎｇ...
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Research on Crystal Structure of the Complex of 10-Hydroxy-10-(3-indolyl)-9-phenanthrenone with Tetrahydrofuran |
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| Meng Ji-Ben,Wen Zhong,Wang Yong-Mei,Wang Ru-Ji,Wang Hong-Gen. Research on Crystal Structure of the Complex of 10-Hydroxy-10-(3-indolyl)-9-phenanthrenone with Tetrahydrofuran[J]. Chinese Journal of Structural Chemistry, 1994, 0(2) |
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| Authors: | Meng Ji-Ben Wen Zhong Wang Yong-Mei Wang Ru-Ji Wang Hong-Gen |
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| Abstract: | The 1:1photoadduct reaction of indole and 9,10-phenanthraquinone(PQ),10-hydroxy-10-(3-indolyl)-9-phenanthrenone(HIPN).forms a 1:1 inclusion complex with tetrahydrofuran (THF)·C_(22)H_(15)NO_2·C_4H_8O,M_r=397.45,space group Pbn2_1,a=11.041(2),b=13.147(3),c=13.958(1),V= 2026(1),Z=4,D_x=1.30g/cm￣3,μ=0.79 cm￣(-1), F(000)=840,R=0.060,Rω=0.067.There are three main planes in the HIPN molecule,the dihedral angles between them are 16.47°,89.21° and 89.83°,respectively.The THF molecule is included through H-bond with the-OH group of HIPN,adopting a unique planar conformation. |
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| Keywords: | crystal structure indole inclusion complex phenanthraquinone. |
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