Raman scattering study of toluene vibrational relaxation in benzene-toluene liquid system |
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| Authors: | W Reimschüssel H Abramczyk H Barańska A ?abudzinska |
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| Institution: | Institute of Applied Radiation Chemistry, Technical University, ?ód?, Poland;Institute of Industrial Chemistry, Warsaw, Poland |
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| Abstract: | The polarizes and depolarized profiles of the 520 cm?1 Raman line of toluene in benzene solutions have been measured as a function of concentration. The vibrational correlation functions were obtained by Fourier inversion of Raman band contours. The concentration dependence of the experimental vibrational correlation time has been compared with that computed from the Fischer-Laubereau vibrational dephasing model modified for use in binary mixtures. |
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