Acid-base equilibrium of anionic dyes partially bound to micelles of nonionic surfactants |
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Authors: | Saikia Palash M Bora Munindra Dutta Robin K |
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Institution: | Department of Chemical Sciences, Tezpur University, Napaam, Tezpur 784 028, Assam, India. |
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Abstract: | The acid-base equilibria of the sulfonephthalein dyes, namely, bromothymol blue, thymol blue, and cresol red, in aqueous nonionic micellar solutions of Triton X-100, Tween-20, Tween-40, Tween-60, and Tween-80 have been investigated. The equilibrium constants of the partition of the dyes between micellar and aqueous pseudophases have been determined spectrophotometrically at fixed pH. The K(ass) increased with the surfactants in the order Tween-80
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