Advancement of isotope separation for the production of reference standards

Idaho National Laboratory (INL) operates a mass separator that is currently producing high purity isotopes for use as internal standards for high precision isotope dilution mass spectrometry (IDMS). In 2008, INL began the revival of the vintage 1970s era instrument. Advancements thus far include the successful upgrading and development of system components such as the vacuum system, power supplies, ion-producing components, and beam detection equipment. Progress has been made in the separation and collection of isotopic species including those of Ar, Kr, Xe, Sr, and Ba. Particular focuses on ion source improvements and developments have proven successful with demonstrated output beam currents of over 10 μA ¹³⁸Ba and 350 nA ¹³⁴Ba from a natural abundance Ba source charge (~2.4 % ¹³⁴Ba). In order to increase production and collection of relatively high quantities (mg levels) of pure isotopes, several improvements have been made in ion source designs, source material introduction, and ion detection and collection. These improvements have produced isotopes of high purity (>98 %) and in quantities in the tens of micrograms per run. The instrument and results for pure isotope production for IDMS standards will be presented.