| Regioselective Propargylation of Aldehydes with Propargyl Bromide Mediated by Sn-In in Aqueous Media under Microwave Irradiation |
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| 引用本文： | Cheng Zhi GU Qian Rong LI Hao YIN. Regioselective Propargylation of Aldehydes with Propargyl Bromide Mediated by Sn-In in Aqueous Media under Microwave Irradiation[J]. 中国化学快报, 2005, 16(12): 1573-1576 |
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| 作者姓名： | Cheng Zhi GU Qian Rong LI Hao YIN |
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| 作者单位： | Structure Research Laboratory, University of Science and Technology of China, Hefei 230026 |
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| 摘 要： | Tin-indium were employed in the propargylations of various aldehydes with propargyl bromide in the presence of SnCl2 and C6H5（CH3）3NBr under microwave irradiation to afford the corresponding homopropargyl alcohols exclusively in high yields. All the reactions were completed smoothly in predominantly aqueous media in 200 seconds only.
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| 关 键 词： | 炔丙基 溴化物 微波放射 锡 碳酰基 结构特征 |
| 收稿时间： | 2005-03-28 |
Regioselective Propargylation of Aldehydes with Propargyl Bromide Mediated by Sn-In in Aqueous Media under Microwave Irradiation |
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| Cheng Zhi GU,Qian Rong LI, Hao YIN. Regioselective Propargylation of Aldehydes with Propargyl Bromide Mediated by Sn-In in Aqueous Media under Microwave Irradiation[J]. Chinese Chemical Letters, 2005, 16(12): 1573-1576 |
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| Authors: | Cheng Zhi GU Qian Rong LI Hao YIN |
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| Abstract: | Tin-indium were employed in the propargylations of various aldehydes with propargyl bromide in the presence of SnCl2 and C6H5(CH3)3NBr under microwave irradiation to afford the corresponding homopropargyl alcohols exclusively in high yields. All the reactions were completed smoothly in predominantly aqueous media in 200 seconds only. |
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| Keywords: | Propargylation aldehydes tin-indium regioselectivity microwave |
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