Electrochemical studies of verdazyl radicals |
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| Authors: | Gilroy Joe B McKinnon Stephen D J Koivisto Bryan D Hicks Robin G |
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| Affiliation: | Department of Chemistry, University of Victoria, Victoria, British Columbia, Canada. |
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| Abstract: | The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and reduction potentials as well as the cell potential (E(cell) = | E(ox) degrees - E(red) degrees |) for these radicals; a correlation between the electron spin distribution and redox properties is developed. |
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