A step forward in gold-silver metallophilicity. An AuAg4 moiety with a square pyramidal arrangement |
| |
| Authors: | Fernandez Eduardo J Laguna Antonio Lopez-de-Luzuriaga Jose M Monge Miguel Montiel Manuel Olmos M Elena Perez Javier Puelles Raquel C Saenz Juan C |
| |
| Affiliation: | Departamento de Quimica, Universidad de La Rioja, Grupo de Sintesis Quimica de La Rioja, UA-CSIC. Complejo Cientifico-Tecnologico, 26004, Logrono, Spain. eduardo.fernandez@dq.unirioja.es |
| |
| Abstract: | By reaction of the Lewis base NBu4[Au(3,5-C6F3Cl2)2] and AgCF3COO in the presence of NBu4CF3COO the heterometallic compound (NBu4)2[Au(3,5-C6F3Cl22Ag4(CF3COO)5] (2) is obtained. The structure displays an unprecendented square pyramidal AuAg4 arrangement built up through four AuAg closed-shell interactions and two Au-C-Ag 3c-2e- bridges. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
