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Preparation and Spectroscopic Characterization of (9Z,9′Z)‐Lutein (Neolutein C)
Authors:Pter Molnr  Erzsbet &#x;sz  Gyula Tth  Ferenc Zsila  Jzsef Deli
Institution:Péter Molnár,Erzsébet Ősz,Gyula Tóth,Ferenc Zsila,József Deli
Abstract:The preparation of pure, crystalline (9Z,9′Z)‐lutein (neolutein C; 2 ) by I2‐catalyzed photoisomerization of (all‐E)‐lutein ( 1 ) is described. The structure of 2 was unambiguously determined by UV/VIS, CD, and NMR spectroscopy, as well as by mass spectrometry, and the complete assignment of the 13C‐NMR spectrum of this carotenoid is presented for the first time.
Keywords:Carotenoids  Lutein  Photoisomerization  Neolutein C
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