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Microchip Capillary Electrophoresis‐Electrochemistry with Rigid Graphite‐Epoxy Composite Detector
Abstract:A new rigid graphite‐epoxy composite electrode for electrochemical detection in microchip electrophoresis is described. The end‐column wall‐jet detection design relying on tubular rigid composite working electrode shows favorably low noise level and high signal‐to‐noise ratio when compared to glassy carbon detector. The performance of rigid graphite‐epoxy composite detector was compared to glassy carbon detector using dopamine and catechol as model analytes. The various parameters of the microchip electrophoresis‐rigid graphite‐epoxy composite detector were optimized.
Keywords:Microchip capillary electrophoresis  Electrochemical detection  Rigid graphite epoxy composite  Glassy carbon electrode  Background noise
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