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Aerobic oxidation of cumene photocatalyzed by iron salts |
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| Authors: | G. V. Nizova G. B. Shul'pin |
| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977 Moscow, Russian Federation |
| Abstract: | Photooxidation of cumene by air in an aqueous emulsion in the presence of Fe(ClO4)3 results in the formation of considerable amounts of acetophenone, the product of the C-C bond cleavage.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1422–1424, June, 1996. |
| Keywords: | photocatalysis metal complex catalysis oxidation with molecular oxygen hydrocarbons cumene peroxides activation of C-H and C-C bonds. |
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