Molybdenum(VI) complexes with N-substituted hydroxylamines |
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| Authors: | A G Beirakhov I M Orlova E G Il’in S G Sakharov L V Goeva A V Churakov M D Surazhskaya Yu N Mikhailov |
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| Institution: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
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| Abstract: | New molybdenum(VI) complexes with N-monoalkylsubstituted hydroxylamines have been synthesized and studied. The structure of MoO2(C2H5NHO)2] and MoO2(i-C3H7NHO)2], whose distinguishing feature is the bidentate chelate coordination of the ligand to molybdenum with the formation of the three-membered NMoO chelate ring, has been determined by X-ray diffraction. |
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