PdCl2-catalyzed hydrogenolysis of a C-O bond in monoaryl sulfates by sodium phosphinate in an aqueous alkaline medium期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

PdCl2-catalyzed hydrogenolysis of a C-O bond in monoaryl sulfates by sodium phosphinate in an aqueous alkaline medium

Authors:	D. V. Davydov I. P. Beletskaya

Affiliation:	(1) M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation

Abstract:	The hydrogenolysis of the C-O bond in monoaryl sulfates by the action of an excess of NaH₂PO₂ in the presence of catalytic amounts of PdCl₂ and KOH is studied. The reaction proceeds chemoselectively with complete ester conversion to the corresponding arenes.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 605–606, March, 1993.

Keywords:	hydrogenolysis monoaryl sulfates palladium catalysis
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