Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal-group 13 metal bond formation |
| |
| Authors: | Steinke Tobias Gemel Christian Cokoja Mirza Winter Manuela Fischer Roland A |
| |
| Institution: | Institut für Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universit?t Bochum, Universit?tsstrasse 150, 44780 Bochum, Germany. |
| |
| Abstract: | Insertion of the carbenoid group 13 metal species InCp* (Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh-Cl bonds of RhCp*Cl2]2] yields the new complexes Cp*Rh(InCp*)3(Cl)2] 1 and Cp*Rh(mu2-Cl)2(InC(SiMe3)3)3] 2, respectively, exhibiting novel cage-like intermetallic complexes with In-Cl-In bridges. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
