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Ni(III) vs. Ni(II)-thiyl radical: charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex |
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| Authors: | Branscombe Neil D J Atkins Andrew J Marin-Becerra Armando McInnes Eric J L Mabbs Frank E McMaster Jonathan Schröder Martin |
| Institution: | School of Chemistry, The University of Nottingham, Nottingham, UK NG7 2RD. |
| Abstract: | Multi-frequency EPR spectroscopy on 61Ni-labelled samples of Ni2(L)]3+ confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II)Ni(III) complex. |
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