Poly(9,9'-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene |
| |
| Authors: | Poriel Cyril Ferrand Yann le Maux Paul Raul-Berthelot Joëlle Simonneaux Gerard |
| |
| Affiliation: | Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes 1, 35042 Rennes, France. |
| |
| Abstract: | Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9'-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
