Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers |
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| Authors: | Shin Dong Mok Lee In Su Chung Young Keun Lah Myoung Soo |
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| Institution: | School of Chemistry, Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea. |
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| Abstract: | Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers. |
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