Solution- and solid-state characterisation of a configurationally-stable beta-diketiminato-supported calcium primary amide |
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| Authors: | Avent Anthony G Crimmin Mark R Hill Michael S Hitchcock Peter B |
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| Institution: | The Chemistry Laboratory, University of Sussex, East Sussex BN1 9QJ, UK. |
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| Abstract: | 'Selective' protonolysis of the beta-diketiminato calcium derivative Ca(NDippCMe)(2)CH]N(SiMe(3))(2)](THF)] Dipp = C(6)H(3)(i)Pr(2)-2,6) with H(2)N(CH(2))(2)OCH(3) produced the dimeric species Ca(NDippCMe)(2)CH]mu-NH(CH(2))(2)OMe]](2), which has been fully characterised in solution and in the solid state. |
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