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Palladium‐Catalyzed Direct Cross‐Coupling of Carboranyllithium with (Hetero)Aryl Halides |
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| Authors: | Ju‐You Lu Hong Wan Jianwei Zhang Zhixuan Wang Yang Li Yongmei Du Chunying Li Prof Zhao‐Tie Liu Prof Zhong‐Wen Liu Prof Jian Lu |
| Institution: | 1. State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, P. R. China;2. Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, P. R. China |
| Abstract: | A palladium‐catalyzed direct C‐arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides. |
| Keywords: | C(cage)− C(sp2) formation carboranyllithium cross-coupling direct C-arylation palladium |