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Pd‐Catalyzed Carboamination of Alkylidenecyclopropanes: Synthesis of Congested Pyrrolidines and Piperidines
Authors:Phillip R Lazzara  Keegan P Fitzpatrick  Dr Chad C Eichman
Institution:Department of Chemistry and Biochemistry, Loyola University Chicago, Chicago, IL, USA
Abstract:The synthesis of densely functionalized N‐heterocycles is an ongoing challenge in chemical synthesis. Herein, we report an efficient method for the construction of pyrrolidine and piperidine scaffolds using a palladium‐catalyzed carboamination of alkylidenecyclopropanes.
Keywords:aminoarylation  carboamination  homogeneous catalysis  nitrogen heterocycles  palladium catalysis
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