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Ru‐Catalyzed Dehydrogenative C−O Bond Formation with Anilines and Phenols |
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| Authors: | Christophe Heitz Alexander W Jones Bünyamin S Oezkaya Christina L Bub Dr Marie‐Laure Louillat‐Habermeyer Victoria Wagner Prof?Dr Frederic W Patureau |
| Institution: | 1. http://www.chemie.uni‐kl.de/patureau;2. FB Chemie, Technische Universit?t Kaiserslautern, Kaiserslautern, Germany |
| Abstract: | The Ru catalyzed cross‐dehydrogenative C?O bond formation between anilines and phenols is described and discussed. The exclusive C?O versus C?N bond‐formation selectivity, moreover in the absence of chelating–assisting directing groups and while leaving the N?H position untouched, is a remarkable feature of this metal‐catalyzed radical cross‐dehydrogenative coupling. |
| Keywords: | aniline C− H activation C− O bond formation cross-dehydrogenative couplings ruthenium |