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Magnetic Composite Lignin Colloids Prepared with a Convenient Patching Method for Generally Treating Heterogeneous Oily Wastewater
Authors:Yating Bai  Yue Kong  Ming Yang  Xing Wang  Dayin Sun  Jinghui Zhou
Affiliation:1. Liaoning Key Laboratory of Pulp and Paper Engineering, Dalian Polytechnic University, Dalian, 116034 P. R. China;2. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China;3. Polymer Institute of Science and Engineering, Department of Chemical Engineering, Tsinghua University, Beijing, 100084 P. R. China
Abstract:The key to the efficient use of biomass resources is the rational design and preparation of lignin-based fine chemicals. In this investigation, the colloidal self-assembly structure formed by lignin in good solvents is used as the module, magnetic Fe3O4 nanoparticles are taken as the carrier, and magnetic composite lignin nanoparticles are prepared in batches by a rapid and convenient surficial grafting (patching) process. The varying amphiphilicity and wettability of lignin are influenced by the various types of wetting solvents. Its wetting behavior can be regulated to achieve oil–water separation in different adsorption or/and emulsification processes. This study provides a novel tool for industrial oil–water separation and, thus, general oily wastewater treatment.
Keywords:composite colloids  lignin  magnetic  oily wastewater treatments  patchy particles
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