Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)3]-[Fe(CN)5NO]·2H2O |
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| Authors: | S. E. Ronco M. E. García Posse P. J. Aymonino O. E. Piro B. E. Rivero R. Mercader E. E. Castellano |
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| Affiliation: | (1) Departamento de Química (Progmma QUINOR) Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Esquina 115, c.c.962, 1900 La Plata, República Argentina;(2) Departamento de Física Facultad de Ciencias Exactas, Universidad National de La Plata, 49 Esquina 115, C.C. 67, 1900 La Plata, República Argentina;(3) Instituto de Física e Química de Sao Carlos, Universidade de Sao Paulo, Caixa Postal 369, 13.560 Sao Carlos, S.P., Brasil |
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| Abstract: | The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP21/n witha=10.072(2),b=19.434(7),c=19.462(3) Å, =101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions. |
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