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Y_(1-x)Nd_xSr_2Cu_(2.7)Mo_(0.3)O_(7-δ)体系的拉曼和红外光谱研究
引用本文:许存义,罗培勋,左健,胡克良,黄允兰,李晓光.Y_(1-x)Nd_xSr_2Cu_(2.7)Mo_(0.3)O_(7-δ)体系的拉曼和红外光谱研究[J].光散射学报,1996(3).
作者姓名:许存义  罗培勋  左健  胡克良  黄允兰  李晓光
作者单位:中国科学技术大学结构分析开放研究实验室
摘    要:利用拉曼散射和红外吸收光谱研究了Y1-xNdxSr2Cu2.7Mo0.3O7-δ(x=0,0.2,0.5,0.8,1.0)系列样品的声子振动性质。实验结果表明,对x=0的样品,在拉曼光谱中主要出现323,443,522和578cm-1几个特征峰,在中红外吸收光谱中出现522,580和646cm-1特征峰。随着样品中Nd组分的增加,323cm-1峰向低波数发生位移,而522和646cm-1峰则向高波数发生位移。本文对这些振动模进行了指认,并对其随不同样品组分的变化行为进行了讨论

关 键 词:拉曼散射  红外吸收光谱  Y1-xNdxSr2Cu2.7Mo0.3O7-δ体系

A Study of Raman Scattering and Infrared Absorption in a Series of Y 1-x Nd xSr 2Cu 2 7 Mo 0 3 O 7-δ Samples
Xu Cunyi,Luo Peixun,Zuo Jian Hu Keliang,Huang Yunlan,Li Xiaoguang.A Study of Raman Scattering and Infrared Absorption in a Series of Y 1-x Nd xSr 2Cu 2 7 Mo 0 3 O 7-δ Samples[J].Chinese Journal of Light Scattering,1996(3).
Authors:Xu Cunyi  Luo Peixun  Zuo Jian Hu Keliang  Huang Yunlan  Li Xiaoguang
Abstract:the phonon vibration characteristics of the series of Y 1-x Nd xSr 2Cu 2 7 Mo 0 3 O 7-δ samples (x=0,0 2,0 5,0 8,1 0) were studied by using Raman spectroscopy and infrared absorption spectroscopy. The typical phonon vibration modes were observed at 323、443、522、578 and 646cm -1 . The 522 cm -1 and 646cm -1 peaks move to higher wavenumber and the 323cm -1 peak moves to lower wavenumber with increasing Nd content x. In this paper, these phonon modes were assigned and their variation behavior with increasing Nd content x were discussed.
Keywords:Raman scattering  Infrared absorption  Y    1-x  Nd  xSr  2Cu    2  7  Mo    0  3  O    7-δ  system
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