Rational modulation of the periodicity in linear hydrogen-bonded assemblies of trimesic acid on surfaces |
| |
| Authors: | Nath Krishna G Ivasenko Oleksandr Miwa Jill A Dang Hung Wuest James D Nanci Antonio Perepichka Dmitrii F Rosei Federico |
| |
| Institution: | Centre Energie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, Varennes, QC, Canada. rosei@emt.inrs.ca |
| |
| Abstract: | We demonstrate a surprising cooperative adsorption process at the liquid-solid interface, involving self-assembly in which a three-fold hydrogen-bonding unit (trimesic acid, TMA) is forced into a linear pattern by noncovalent interaction with an alcohol. Our work shows that the unexpected linear pattern formed by coadsorption of TMA and alcohols can be modulated in size by choosing alcohols with different chain lengths. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
