| 混合型杂多化合物M_x[GaW_9M_3O_(40)]·nH_2O的合成和性质 |
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| 引用本文： | 刘景福,王敬平,瞿伦玉,陈亚光.混合型杂多化合物M_x[GaW_9M_3O_(40)]·nH_2O的合成和性质[J].无机化学学报,1992(3). |
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| 作者姓名： | 刘景福 王敬平 瞿伦玉 陈亚光 |
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| 作者单位： | 东北师范大学化学系，东北师范大学化学系，东北师范大学化学系，东北师范大学化学系 长春 130024，长春 130024，长春 130024，长春 130024 |
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| 摘 要： | 本文报道了M_xGaW_9M_3~′O_(40)]nH_2O(M′=Mo,V,Ti,Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Mn(Ⅱ);M=k,Na,Gua,Me_4N,Et_4N,Bu_4N)的合成。通过元素分析,阴离子电荷的确定,极谱、IR及UV光谱、可见光谱、ESR、磁化率测定对其进行了表征。并研究了它们在水溶液中对酸碱的稳定性及热稳定性。
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| 关 键 词： | 镓钨杂多化合物 混合型杂多化合物 性质 过渡元素 |
SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLY COMPLEXES M_x[GaW_9M'3O_(40)]?nH_2O |
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| Liu Jingfu Wang Jingping Qu Lunyu Chen Yaguang.SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLY COMPLEXES M_x[GaW_9M''''3O_(40)]?nH_2O[J].Chinese Journal of Inorganic Chemistry,1992(3). |
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| Authors: | Liu Jingfu Wang Jingping Qu Lunyu Chen Yaguang |
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| Abstract: | Trisubstituted heteropoly complexes MxGaW9M'3O40] ?nH2O have been prepared and characterized by elemental analyses, charge determination on anions, polarograph, IR and UV and Vis spectra, ESR and magnetic susceptibility. Their thermal stability and stability in solution have been also examined. |
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| Keywords: | trisubstituted heteropoiy complex tungstogallate characterization transition element |
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