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Magnetic instabilities in Fe3C cementite particles observed with Fe K-edge x-ray circular dichroism under pressure
Authors:Duman E  Acet M  Wassermann E F  Itié J P  Baudelet F  Mathon O  Pascarelli S
Institution:Experimentalphysik, Universit?t Duisburg-Essen, D-47048 Duisburg, Germany.
Abstract:The ferromagnetic interstitial iron compound Fe(3)C (cementite) is expected to have Invar properties, whereby a high-moment to low-moment transition should occur when the atomic volume is reduced below a critical value. We, therefore, examine the pressure dependence of the Fe K-edge x-ray magnetic circular dichroism in Fe(3)C at ambient temperature and pressures up to 20 GPa. We find clear evidence for a high-moment to low-moment transition around 10 GPa.
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