Synthesis and comparative characteristic of organophosphorus dendrimers with phenoxy and deuterophenoxy end groups |
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| Authors: | C Padie C -O Turrin A -M Caminade J -P Majoral V L Furer I I Vandyukova V I Kovalenko |
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| Institution: | (1) National Scientific Research Center (CNRS), Toulouse, France;(2) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
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| Abstract: | Two series of generation 0 to 6 phosphorus dendrimers (6 to 384 end groups) are synthesized starting from the cyclotriphosphazene core. The series are distinguished by the type of their terminal groups: O-C6H5 in first series and O-C6D5 in the other. These functions are chemically analogous, but they give different spectroscopic signatures which afford detailed information about the structure of these dendrimers. |
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