Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations |
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Authors: | Müller Achim Toma Liviu Bögge Hartmut Henry Marc Haupt Erhard T K Mix Andreas Sousa Filipa L |
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Institution: | Fakult?t für Chemie der Universit?t, Postfach 100131, 33501, Bielefeld, Germany. a.mueller@uni-bielefeld.de |
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Abstract: | In the cavities of unprecedentedly functionalised, spherical, porous capsules of the type {Pentagon}12{Linker}30 identical with {(Mo)Mo5O21(H2O)6}12{Mo2O4(ligand)}30]n- reactions with the ligands -i.e. at the internal shell surfaces - can be performed, in the present case deliberate aquation/hydration and deprotonation reactions at the linker fragments {(Mo2O4)C2O4H}+ similar to that reported in the literature for (NH3)5CoC2O4H]2+ in solution. |
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