Complementary short syntheses of (±)-methyl shikimate |
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Authors: | Malcolm M Campbell Aston D Kaye Malcolm Sainsbury Roya Yavarzadeh |
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Institution: | School of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, U.K. |
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Abstract: | Two syntheses of (±)-methyl shikimate from the adduct of furan and methyl acrylate are described. One requires the regioselective hydroxylation of (±)-5β,6β-dihydroxy-,-isopropylidene-2-methoxycarbonylcyclohexa-1,3-diene and the other -dihydroxylation of (±)-5-hydroxy-1-methoxycarbonylcyclohexa-1,3-diene. |
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