A method for the palladium-catalyzed allylic oxidation of olefins |
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| Authors: | John E McMurry Pavel Kočotovský |
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| Institution: | Department of Chemistry, Baker Laboratory Cornell University, Ithaca, NY 14853 U.S.A |
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| Abstract: | Olefins are converted into allylic acetates by treatment in acetic acid with a catalytic amount of palladium bis(trifluoroacetate) and one equivalent of benzoquinone as oxidant. The reaction is selective for oxidation of a terminal methyl group of geranylacetone. |
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