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Biosynthesis of citreothiolactone,citreopyrone and pyrenocine B

Authors:	Yoshikazu Shizuri Seiji Kosemura Shosuke Yamamura Hideyuki Furukawa Kazuaki Kawai Nobuo Okada

Institution:	Department of Chemistry, Faculty of Science and Technology, Keio University Hiyoshi, Yokohama, Japan;Faculty of Pharmacy, Meijo University, Tempaku-ku, Nagoya, Japan

Abstract:	¹³C NMR spectroscopy using INADEQUATE pulse sequence method has been used to deduce the labelling patterns of the three metabolites of $Penicillium citreo-viride$ B. derived from 1,2-¹³C]acetate, indicating that their carbon skeletons consist of two different units CH₃COCH₂COCH₂COS-Enzyme and CH₃COCH₂COS-Enzyme].

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